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Hikaru's diary on learning to solder Hikaru's diary on learning to solder
STORY 8: Hikaru Meets Mr. Yokoo again
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Mr.Yokoo : Then, the liquid component that has melted flows into the inner part of the gap but the component that has not melted is left. This phenomenon is called "separated melting". This phenomenon causes the joint strength and corrosion resistance to deteriorate.
Hikaru : I see. I get the picture.
Soldering is to fill solder into a gap between target metals.
Mr.Yokoo : The same phenomenon occurs when the solder hardens from the liquid state. Even if it looks hardened, it may not have completely hardened yet. If the target metal is moved in such a condition, a soldering failure occurs. "Eutectic" means a composition with the lowest melting point and with no difference between the melting temperature and the hardening temperature. Therefore, as with pure substance, eutectic solder will instantaneously melt and harden at a constant temperature. Do you understand this?
Hikaru : I understand it completely.
Mr.Yokoo : OK, you learn quickly. In passing, I'll briefly explain about lead-free solder now.
Well, Hisasi.
Hikaru : I'm Hikaru.
Mr.Yokoo : Don't worry about the details. Do you know why lead-free soldering is required?
Hikaru : That's because lead is harmful to the body.
Mr.Yokoo : That's right. Lead has toxicity that affects the central nervous system in the human body. But, lead was contained in face powder and pigment in the past. Now, lead is not used for that because its toxicity was proven. Lead caused Kabuki actors to suffer from a kind of occupational disease at that time. By the way, do you know that lead was also used in tap water piping in the past?
Hikaru : What?! That is terribly dangerous, isn't it?
Mr.Yokoo : No, it is not always dangerous. When lead is combined with carbonic acid and oxygen dissolved in water, a film of lead compound (2PbCO3EPb(OH)2) is deposited on the inner surface of the lead pipe. Because this compound is not soluble in water, it prevents lead from dissolving into the water. Tap water was clean in the past.
Hikaru : Is lead used in tap water piping even now?
Mr.Yokoo : It is not used now. Because the water quality has deteriorated, a large quantity of disinfectant is contained in tap water and the lead compound film is difficult to deposit on the inner surface of the lead pipe.
Hikaru : I see.

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